Abstract:The nano-mechanical and friction/wear properties of SiC(silicon carbon) thin film deposited on Mg alloy(AZ91D) substrate using magnetron sputtering technique at room temperature were investigated with a Nano Indenter and a friction and wear tester.The results show that the SiC film exhibites a low nano-hardness(12.39 GPa) and Young′s modulus(78.93 GPa) but a high ratio of hardness to modulus(0.157).The film-substrate system exhibites good friction/wear properties with the friction coefficient of about 0.248 and the special wear rate in the order of 10-5mm3·m-1·N-1 together with little film cracking and interface delamination when sliding against Si3N4(silicon nitride) ball using ball-on-disc frictional and wear tester under dry frictional condition.The high wear-resistance is in accordance with low hardness,high hardness-to-modulus ratio and good film-substrate modulus match.The abnormal nano-mechanical behaviors are believed to be due to the high activity and low melting point of the substrate magnesium.