Abstract:Using three-dimensional diffusion theory, the homogenization treatment of newly-developed as-cast Ni - Cr - Mo - Cu alloys and evolutions of its microstructure and properties were studied. The results showed that the coarser as-cast microstructures from three melting methods, hand-arc furnace(fine cellular structures about 20 μm cell size), vacuum induction furnace (coarse dendritic structures about 80 100 μm spacing)and consumable electrode vacuum arc furnace( well-developed directional dendrites about 60 - 80 μm spacing) , all disappeared and segregated mierostruetures were homogenized after solution treatment at 1 140 - 1 170 ℃ for 2.5 h. Compared with the as-cast alloys, the corrosion resistance of the as-solution alloys in four kinds of typical corrosive agents was improved ( above 15% - 25% ). Both hardness and strength were increased by about 30%. The present Ni - Cr - Mo - Cu alloy has excellent corrosion resistant ability, especially in FeCl3 and HCl solutions, about 2 - 3 orders as high as 1Cr18Ni9Ti. Through analysis of the Fourier series solution for diffusion equation, the semi-experiential formula of solution treating time was derived for the as-cast Ni - Cr - Mo - Cu alloys.
杨瑞成, 牛绍蕊, 王凯旋. 镍基耐蚀合金扩散均匀化处理及组织性能演变[J]. 江苏大学学报(自然科学版), 2009, 30(1): 32-35.
Yang Ruicheng, Niu Shaorui, Wang Kaixuan. Diffusional homogenization treatment of Ni - Cr - Mo - Cu corrosion resistance alloy and evolutions of its microstructure and properties[J]. Journal of Jiangsu University(Natural Science Eidtion)
, 2009, 30(1): 32-35.