Impact of fatty acid methyl ester upon cold flow properties for biodiesel
1. School of Automohile and Traffic Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China; 2. Key Laboratory of Food Sci ence and Safety, Ministry of Education, Jiangnan Univcrsitv Wuxi, Jiangsu 214122, China; 3. School of Energy and Power Engineering, Jiangsu Univcrsity, Zhenjiang, Jiangsu 212013, China
Abstract:Impact of composition upon the cold flow properties for biodiesel was investigated with gas chromatography-mass and cold filter plugging point tester based on the theories of molecular structure and crystal growth. Biodiesel may be considered a pseudobinary mixture consisting of components, with high- melting-point saturated fatty acid methyl esters and with low-mehing-point unsaturated ones. The results show that biodiesel is mainly composed of saturated fatty acid methyl esters( C14:0 - C24:0 ) and unsaturated ones(C16:1 -C22:1, C18:2 and C18:3 ). The cold flow properties for biodiesel are determined mainly by saturated fatty acid methyl esters. Long-straight-chain saturated fatty acid methyl ester tends to have rela- tively poor cold flow properties. Controlling saturated fatty acid methyl ester contents can improve cold flow properties of biodiesel.