Hydrothermal synthesis and crystal structure of a new manganese complex [Mn （PyPhen） 2Cl2]
1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China; 2. School of Chemistry, Jilin Normal University, Siping, Jitin 136000, China）
Abstract：A new complex [ Mn （PyPhen）2Cl2] based on the pyrazino [ 2,3 -f] [ 1,10 ] phenanthroline （PyPhen） ligand was hydrothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X ray diffraction. The title compound crystallizes in monoclinic space group C2/c, with α = 0.847 47（10） nm, b=1.251 29（14） nm, c=2.2705（3） nm, β = 94. 955 0（10）°, V=2.398 8（5） nm3, Z=4, R1 =0.037 4, wR2 =0.0914. The manganese （II） atoms in distorted octahedral coordination geometries. [ Mn （PyPhen）2Cl2 ] is stacked between the PyPhen ligands to form a 3D supermolecular architecture. [ Mn （ PyPhen）2Cl2] have through π-π interactions
车广波, 李秀颖, 徐占林, 刘春波, 闫永胜. 新型锰配合物[Mn（PyPhen）2Cl2]的水热合成与晶体结构[J]. 江苏大学学报（自然科学版）, 2009, 30(3): 306-308.
Che Guangbo, Li Xiuying, Xu Zhanlin, Liu Chunbo, Yan Yongsheng. Hydrothermal synthesis and crystal structure of a new manganese complex [Mn （PyPhen） 2Cl2][J]. Journal of Jiangsu University(Natural Science Eidtion)
, 2009, 30(3): 306-308.
2009, Vol. 30 
